No, Chris Evans does not show up in the movie. His character Steve Rogers is mentioned, naturally, but the man himself does not appear (not even in the photos Sam keeps at his work station, which is a bit weird,

Brave New Soldier follows in the footsteps of three installments for Chris Evans’ Steve Rogers and four Avengers films when Rogers recruited Thor, Iron Man, Black Widow, Thor, The Incredible Hulk and more to combat threats to the world and universe.

Sam Wilson and Bucky Barnes. Anthony Mackie and Sebastian Stan. Falcon, now Captain America and the Winter Soldier. Anyway, however you want to name this duo, it’s a pretty iconic one.